JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
Materials Engineering and Interfacial Phenomena
Smart Preparation of Polydiacetylene Hydrogel Based on Self-Assembly of Tricosadiynoic Acid and 1-Oleoylglycerol (Monoolein)
Keishi Suga Yoko OtsukaKengo YoshidaHiroshi Umakoshi
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2019 Volume 52 Issue 3 Pages 311-316

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Abstract

Polydiacetylene (PDA) shows a unique colorimetric response toward external stimuli, such as heat. Herein, self-assembled hydrogels were prepared by 10,12-tricosadiynoic acid (TCDA) and 1-oleoylglycerol (Monoolein, MO). The hydrogel of TCDA/MO (1/1) turned to blue by UV irradiation, and the color changed to red by heating. Although unpolymerized gel deformed within 3 h at 70°C, the polymerized hydrogel maintained its structure at least for 4 h. This method successfully produced hydrogel materials including the organized membranes composed of PDA precursor molecules.

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© 2019 The Society of Chemical Engineers, Japan
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