Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Special Article: The 58th CerSJ Awards for Academic Achievements
Design and Synthesis of New Functional Materials Using the Interstices of Inorganic Host Structure
Shoji YAMANAKA
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2004 Volume 112 Issue 1308 Pages 421-427

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Abstract
Effective use of the interstices of inorganic host structures is the key to develop new functional materials. The interstices in layer structured crystals are most versatile; the reaction concerning the interlayer space is called intercalation. Some examples of new functional materials developed using interstices are briefly reviewed, such as clay-organic complexes, porous pillared materials, interlayer grafting, anion exchangeable compounds, and layer structured nitride superconductors. A new silicon clathrate superconductor with a Si-sp3 cage structure is also introduced.
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© 2004 The Ceramic Society of Japan
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