Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Preparation and Conductivity Measurements of the CuCl-Cu2MoO4-CuPO3 Glasses
Nobuya MACHIDAShinji TSUCHIDATsutomu MINAMIToshihiko SHIGEMATSUNorihiko NAKANISHI
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1992 Volume 100 Issue 1157 Pages 104-106

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Abstract
Cu+ ion-conducting glasses were prepared in the pseudoternary system CuCl-Cu2MoO4-CuPO3. These glasses showed high ion conductivities of the range of 100 to 10-4Sm-1 at room temperature. The conductivities of these glasses increased with an increase in the CuCl content at a given composition parameter y, which denotes the ratio of the number of phosphorus atoms to the total number of phosphorus and molybdenum atoms in the glasses, y=[P]/([P]+[Mo]). For the glasses with a low and constant CuCl content the conductivities steeply decreased with an increase in y, while the conductivities gradually or almost independently changed with an increase in y for the glasses containing a constant and large amount of CuCl.
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