Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Reduction of Lead Leaching from Overglaze Decoration by Treatment with a Weak Acid
Toyohiko SUGIYAMAKeisuke MIZUNOTatsuro HORIUCHIToshihiko OSAKIHiroyuki MASUDAKenzi SUZUKI
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1997 Volume 105 Issue 1221 Pages 406-411

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Abstract
The lead leaching from overglaze decoration was greatly reduced after soaking in 4% acetic acid for 10 to 24h. The effectiveness of the treatment in reducing the lead leaching was confirmed. Most overglaze decorations showed no change in gloss or color after the treatment with acetic acid. The reduced gloss in some overglaze decorations after the treatment could be recovered by reheating at 300 to 500°C. The low level of lead leaching achieved by the treatment was retained even after reheating up to 800°C. For studying the mechanism of lead leaching, the surface of overglaze decoration was observed by optical microscopy and EPMA. It was observed that particular regions in the overglaze decoration releasing large amounts of lead were eroded by acetic acid.
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