Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Sr Substitution Effect in Ba-Y-Cu-O System
Takuya UZUMAKIKazunori YAMANAKAAtsushi TANAKANobuo KAMEHARAKoichi NIWA
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1988 Volume 96 Issue 1112 Pages 517-520

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Abstract
We fabricated Sr-Ba-Y-Cu-O ceramics that consists of Sr:Ba:Y:Cu=8x:8(1-x):2:10, where x=0, 0.125, 0.25, 0.375, 0.5 and 0.75, for the purpose of studying the effects of Sr substitution on Ba-Y-Cu-O crystal structure, the electrical and magnetic properties, and the microstructure. By observing the microstructure, it was learned that as the Sr component increases, the grain size of the samples decreases gaining density. The Sr concentration dependence of the lattice constants shows orthorhombic-tetragonal phase transition at x=0.5. The critical onset temperature, Tco decreases as the Sr component increases. However, at x=0.5, when the Tco increases, the resistivity at the room temperature shows the minimun value.
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