Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
Special Articles: The 61th CerSJ Awards for Acsdemic Achievement in Ceramic Science and Technology: Reviews
Synthesis of ceramic nanoparticles with non-equilibrium crystal structures and chemical compositions by controlled thermal plasma processing
Takamasa ISHIGAKI
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2008 Volume 116 Issue 1351 Pages 462-470

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Abstract
The synthesis of functional nanostructured powders has been developed through reactive thermal plasma processing. Nanosized particles of titanium oxide powder with high crystallinity and non-equilibrium chemical composition were synthesised by one-step processing based on the oxidation of solid and liquid precursors. Spherical carbon powders were treated in a reactive thermal plasma. Crystallinity, chemical composition, and surface morphology were changed in plasma-treated carbon powders. Plasma-treated carbon powders were used as the anode of a lithium-ion rechargeable battery, and improvements in discharge capacity and efficiency were recognized. The generation of pulse-modulated RF inductively coupled plasmas (PM-ICPs) was developed for the first time. The non-equilibrium states were recognized at the instances of pulse-on and pulse-off, and the concentration of chemically active radical species was increased. This offers a unique physico-chemical condition for materials processing.
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© 2008 The Ceramic Society of Japan
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