Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
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Electrical properties of ternary metal-rich telluride Pd2NiTe2
Shin KIKUCHIMakoto WAKESHIMAYukio HINATSU
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2009 Volume 117 Issue 1361 Pages 27-31

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Abstract
A ternary metal-rich telluride Pd2NiTe2 has been prepared by the solid-state reaction. This compound crystallizes in the orthorhombic K2ZnO2-type structure with space group Ibam. In this structure, the Ni atom is tetrahedrally coordinated and the NiTe4 tetrahedra share edges forming one-dimensional chains with short Ni-Ni bondings along the c-axis. Through magnetic susceptibility, specific heat, and electrical resistivity measurements, this compound shows Pauli paramagnetism and metallic electrical conductivity. The electronic structure calculation of Pd2NiTe2 suggests that its electrical conductivity is a three-dimensional one, which is caused by conduction bands originated from d orbitals of Pd and Ni and p orbitals of Te.
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© 2009 The Ceramic Society of Japan
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