Chemical recycling of municipal waste slag by using phase separation

Abstract

A chemical recycling method by using phase separation was applied to municipal waste slags. Glasses were prepared from incineration ash and ash-melted slag, where B₂O₃ was added to promote phase separation. The glasses were heat-treated at temperatures higher than their glass transition temperatures, and they were soaked in hydrochloric acid, leaching CaO, Fe₂O₃, K₂O, and S. Transparent and colorless solids containing ca. 80 mass% of SiO₂ were successfully obtained as residues. It was suggested that phase separation took place not in the heat-treatment but in the vitrification process, and further characterizations are however required to investigate the phenomena at microscopic levels in the recycling processes.