Non-uniformity of shrinkage rate as a function of current acceleration during flash event under voltage-to-current protocol in 8 mol %Y₂O₃–ZrO₂

Abstract

This study verified the behavior of sample current, volumetric power dissipation, and shrinkage during flash sintering with the voltage-to-current protocol in the time frame of 90 s before and after the flash event. The volumetric power dissipation exhibited a peak value, followed by a decrease to the minimum value, and then increased asymptotically and approached a steady-state value. The discrepancy between the peak and minimum values, ΔP, increased with the limiting current value pre-set at the power supply during the heat-up stage. As ΔP increased, the degree of shrinkage progress decreased in stage III after the flash event, which is caused by the heterogeneity of shrinkage rate inside a compact. To consider the complete shrinkage amount, including stage III, in the current-to-voltage protocol, it is crucial to ensure that ΔP does not reach an excessive level when setting the maximum current.