Nihon Kessho Gakkaishi
Online ISSN : 1884-5576
Print ISSN : 0369-4585
Part 2. Crystal Structure and Physical Properties of Minerals in the Earth's and Planetary Interior
High-pressure Single-crystal X-ray Diffraction Study on Minerals Related to the Earth's Mantle:
Pressure-induced Phase Transformation of Spinel Minerals with Jahn-Teller Effect
Atsushi KYONO
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2018 Volume 60 Issue 1 Pages 32-39

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Abstract

High-pressure single-crystal X-ray diffraction measurement of cuprospinel CuFe2O4 was performed at beamline BL10A at the Photon Factory, KEK, Japan. With increasing pressure, the Cu position in the octahedral site moves toward the center of the octahedral coordination, which approaches to the regular octahedral geometry. This geometrical modification enhances the repulsion between eg orbital from the Cu2+ and electrons from the ligand oxygen atoms. At 4.6 GPa, the cuprospinel with cubic structure is consequently transformed to a tetragonally distorted structure, in which the octahedral coordination is elongated along the c-axis with the Jahn-Teller effect of Cu2+.

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© 2018 The Crystallographic Society of Japan
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