Nihon Kessho Gakkaishi
Online ISSN : 1884-5576
Print ISSN : 0369-4585
ISSN-L : 0369-4585
Valence Difference Detected by X-Ray Anomalous Scattering
Satoshi SASAKI
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1997 Volume 39 Issue 1 Pages 37-44

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Abstract
Diffraction and scattering experiments at x-ray wavelengths close to an absorption edge has made it possible to distinguish even different valence states. Anomalous scattering factors derived from the XANES absorption data and the chemical shift show that the difference between f' (Fe2+) and f' (Fe3+) reaches up to 2.5. Here we demonstrate the possibility of va-lence-difference contrast methods.
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© The Crystallographic Society of Japan
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