2020 Volume 59 Issue 1 Pages 48-53
The microstructural evolution and strengthening of Cu–20 at.% Ni–6.7 at.% Al alloy during isothermally aging at 450 to 650℃ were investigated to understand age–induced precipitation and hardening behavior for Cu–Ni–Al system. In an initial stage of aging, fine ordered Ni3Al particles with a size of several tens nm was coherently formed in parent grains of Cu solid solution in a continuous precipitation manner, together with cellular components composed of Cu solid solution and fine fibrous Ni3Al phases by grain boundary reaction. During furthermore aging, fine Ni3Al particles in grains were continuously nucleated and grown, while cellular components at grain boundaries seemed not to be developed. The alloy exhibited a maximum hardness more than 320 Hv by aging at 550 to 650℃, which was greatest among conventional copper alloys. The hardening in the alloy was principally contributed to a high–density dispersion of fine ordered Ni3Al particles in grains. According to the time–temperature transformation (TTT) diagram for the alloy, aging at 600 to 650℃ should be effective to obtain a microstructure with fine dispersion of ordered Ni3Al particles and without cellular components, resulting in an excellent strength with the alloy.