2001 Volume 80 Issue 2 Pages 97-105
In order to study nitrogen release from different nitrogen functionality, two types of model coals with different nitrogen structures have been prepared using cellulose and phenolic nitrogen compounds, 2-hydroxycarbazole and 6-hydroxyquinoline. Carbon and nitrogen structures in the model coals have been analyzed by solid-state 13CNMR, pyrolysis GC-NPD and GC-MS. The 13C-NMR spectra of the model coals very closely resemble those of natural coals with similar carbon content, and the pyrolysis GCNPD analyses show that the model coals have the same nitrogen-containing skeleton as the original nitrogen compounds.
Addition of Ca and Fe catalysts on the model coals has also been carried out to make clear the effects of the Ca and Fe on nitrogen release from the model coals. Nitrogen release during pyrolysis of the model coals without and with catalyst has been studied in a fixed-bed reactor at 50°C/min up to 1, 000°C. The pyrolysis results show that thermal decomposition behavior of pyrrolic and pyridinic nitrogen in the model coals is similar, and both calcium and iron catalysts are effective on nitrogen removal from the model coals prepared at 200°C. However, the efficiency of nitrogen removal by the catalysts depends on the preparation temperature of the model coals.