Influence of H₂ additive on Hg/Ar gas mixture discharges: Boltzmann equation analyses

Abstract

The electron swarm parameters in Hg/Ar and Hg/Ar: 0.1%H₂ mixtures are analyzed using a Boltzmann equation in which the generation of secondary electrons through Penning and cumulative ionization, and collisions between two metastable Hg (Hg*) atoms are taken properly into consideration. The present values of the Townsend first ionization coefficient and the concentration of Hg* agree well with the experimental values of Burgumann et al and Bigio respectively. It is shown that mixing 0.1%H₂ in Hg/Ar lowers the ionization coefficient significantly. This lowering effect is discussed how it influences the characteristics of discharge lamps.