1-3-1 固体酸触媒を用いた低級オレフィンのアルキレーション反応(1-3 合成・その他,Session 1 石炭・重質油等,研究発表)

阿部 祥之; 岸 容平; 朝見 賢二; 藤元 薫

doi:10.20550/jietaikaiyoushi.18.0_18

Proceedings of the Annual Conference of The Japan Institute of Energy

Online ISSN : 2423-8325
Print ISSN : 2423-8317
ISSN-L : 2423-8317

[volume title in Japanese]

Session ID : 1-3-1

DOI https://doi.org/10.20550/jietaikaiyoushi.18.0_18

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Name : [in Japanese]

Location : [in Japanese]

Date : July 30, 2009 - July 31, 2009

1-3-1 Alkylation of isobutane with low-molecular-weight olefin with solid catalyst

Yoshiyuki ABE, Yohei KISHI, Kenji ASAMI, Kaoru FUJIMOTO

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CONFERENCE PROCEEDINGS FREE ACCESS

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Abstract

Alkylation reaction of isobutane with ethylene was performed over modified beta zeolite catalysts with a semi-batch reaction system at 100℃ and 2.5MPa. Three kinds of metal (Pt, Pd, and Cu) added zeolite catalysts were used in this study. The Copper-added catalyst showed the highest alkylation activity among them. Lower Cu loading and lower SiO2/Al2O3 ratio of beta zeolite were favored for the formation of alkylate products such as C6 and C8 hydrocarbons.

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