Proceedings of the Annual Conference of The Japan Institute of Energy
Online ISSN : 2423-8325
Print ISSN : 2423-8317
ISSN-L : 2423-8317
[volume title in Japanese]
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1-4-2 Rate analysis of air oxidation of coal at low temperatures
Kouichi MiuraHideaki OHGAKINobuyuki SatoMasaharu Matsumoto
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Pages 26-27

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Abstract

This work successfully measured heat generation rates accompanying the air oxidation at 50 to 150 °C for 3 kinds of low rank coals using a TG-DSC analyzer. The heat generation rates measured were well expressed by 3 parallel first order reactions which have the activation energies of several kJ/mol, 10 to 15 kJ/mol, and 55 kJ/mol for all of the coals. It was also found that 200 to 350 kJ/kg of heat is generated when the coals are exposed to air at 150 °C for 30 min. The heat is big enough to raise coal temperature by 150 to 260 °C under adiabatic conditions. The rate equations were well expected to be utilized for the prediction of actual temperature increase.

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© 2017 The Japan Institute of Energy
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