Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Paper
BiCl3, CuCl2 Intercalation into HOPG
Ryusei OtsukiKentaro Ohhashi
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JOURNAL OPEN ACCESS

2006 Volume 53 Issue 12 Pages 955-959

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Abstract
BiCl3 and CuCl2 reacted with HOPG (Highly Oriented Pyrolytic Graphite) in the various conditions. In the reaction of BiCl3 with CuCl2GIC, the only stage4 BiCl3GIC was obtained. In the reaction of CuCl2 and BiCl3 with HOPG, the coexistent substance of stage2 or 4 BiCl3GIC and stage2 or 4 CuCl2GIC was obtained. Composition of Cu and Bi was C20(CuCl2)0.74(BiCl3) in the case of mol ratio CuCl2:BiCl3=6:1 with the vacuum tube reaction, and was C11.76(CuCl2)2.08(BiCl3) in the case of 3:1.
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© 2006 by Japan Society of Powder and Powder Metallurgy

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