Syntheses of Silicate Phosphors by Aqueous Solution Techniques using Water-Dispersible Inorganic Si Cluster

Abstract

ABSTRACT

In this paper, we demonstrated the synthesis of silicate-based phosphors by solution techniques using glycol-modified silane (GMS) as a Si source. GMS is a water-dispersible inorganic Si cluster, which is vitally involatile and nonflammable compounds, compared to volatile and flammable Si-alkoxides such as tetraethoxysilane (TEOS). Therefore, GMS has allowed the silicon containing compounds to be synthesized through various solution processes for ceramic compounds such as polymerizable complex (PC) and amorphous metal complex (AMC) methods. This paper provides examples of synthesis of new silicate-based phosphors such as NaAlSiO₄:Eu²⁺, BaZrSi₃O₉:Eu²⁺, and CaSrSiO₄:Eu²⁺. In addition, other examples of improvement of emission for conventional silicate-based phosphors, Y₂SiO₅:Ce³⁺-Tb³⁺ and Zn₂SiO₄:Mn²⁺, prepared by the above solution techniques including homogeneous precipitation using GMS are also given in this paper.