Journal of the Japan Society of Powder and Powder Metallurgy
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
Preparation of Lithium Ion Conducting Composites with Amorphous 60Li2S⋅40SiS2 and Thermo-elastic SEPS (Styrene-ethylene-propylene-styrene)Co-polymer
Sayo KatouNobuya MachidaYoshiyuki IkedaToshihiko Shigematsu
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JOURNAL OPEN ACCESS

2002 Volume 49 Issue 11 Pages 974-983

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Abstract
Organic-Inorganic composites were prepared as lithium ion conducting materials. Organic thermo-elastic co-polymer SEPS (styrene-ethylene-propylene-styrene) and inorganic lithium ion conductor a-60Li2S⋅0SiS2 (mol%), which was prepared by mechanical milling processes, were used as raw materials for the preparation of the composite materials. The mixture of the raw materials were heated at 90°C under a pressure of about 3×107 Pa for 1 h to obtain the composite materials in sheet shape. The obtained composite sheet containing 7wt% of SEPS showed ion conductivity 4.9×10-5 Scm-1 at room temperature. Electronic polarization measurements suggested that the main carrier of the composite sheet was lithium ions and that the ion transport number of the sheet was almost unity.
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