Abstract
Geochemical characteristics in groundwater such as groundwater chemistry and physicochemical parameters are affected by their source and the interaction with rocks and minerals. We observed the relationships between groundwater chemistry of the deep-groundwater and the geology in non-volcanic areas in Japan using about 9300 of deep-groundwater data. A Geographical Information System (GIS) was used to extract data in non-volcanic areas and numbers of water data are about 5200. The data were further classified into four types of geology (sedimentary rock, accretionary complex, volcanic rock and plutonic rock). The pH, temperature and major ion concentrations among deep-groundwaters in each geology have been statistically analysed. Result shows that the total cation concentration of deep-groundwaters are significantly different between geology, and the average values are decreased in the order of the sedimentary rock (66.7 meq l-1), volcanic rock (43.0 meq l-1), accretionary complex (24.6 meq l-1), and plutonic rock (11.0 meq l-1). The average pH does not show the major difference between geology whereas the highest average temperature is found in volcanic rock. In addition, the all four major cations (Na, K, Mg, and Ca) show the highest average concentrations in sedimentary rock, within the highest average concentrations of major anions for Cl, SO4, and HCO3 are found in sedimentary rock, volcanic rock and accretionary complex, respectively, indicating the difference of the influence on the anions varied with geology. The distribution of deep-groundwater that are dominated by each major anions implied that SO4-type groundwater in volcanic rocks are formed by the influence of Neogene volcanic rock (Green tuff). In addition, HCO3-type groundwater in accretionary complex found from Kinki to Shikoku regions are formed by the addition of CO2 gases supplying not only from surface soil and carbonate minerals but from deep underground.
