Abstract
We formulate a conserving gapless mean-field theory for Bose–Einstein condensates on the basis of a Luttinger–Ward thermodynamic functional. It is applied to a weakly interacting uniform gas with density n and s-wave scattering length a to clarify its fundamental thermodynamic properties. It is found that the condensation here occurs as a first-order transition. The shift of the transition temperature ΔTc from the ideal-gas result T0 is positive and given to the leading order by ΔTc=2.33an1⁄3T0, in agreement with a couple of previous estimates. The theory is expected to form a new theoretical basis for trapped Bose–Einstein condensates at finite temperatures.