1970 Volume 28 Issue 4 Pages 965-975
Measurements of electro-absorption of thin CdS crystals are carried out in the temperature range from 85 to 300°K around the photon energy of the fundamental absorption edge. At 300°K, the spectra show characteristics due to the Urbach-rule edge at low photon energies, while oscillatory behaviors of the spectra are observed at high photon energies. The reduced effective masses assoiated to Γ9−Γ7 and Γ7−Γ7 transitions in CdS are estimated from the dependence of the change in the absorption coefficient on the applied electric field. The spectra of the change at 85°K are concluded to consist of superposition of those related to A1− and B1− excitons, since the wavelengths at maximum peaks in oscillatory curves of the change of the absorption coefficient at the extrapolated zero-field are consistent to the above exciton wavelengths assigned from results of photoconductivity by Park-Reynolds.
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