Resonant Raman Scattering in (E×e) Jahn-Teller System

Abstract

The excitation spectrum for the resonant Raman scattering in the (E×e) Jahn-Teller system is calculated by using two different methods. The first is the classical method based on the configuration coordinate model (CCM), and the second is the numerical method based directly on the Heisenberg-Kramers formula. As far as the first order Raman scattering process is concerned, the two kinds of results agree well in the strong coupling limit. These results are also compared with the experiment on C₆O₆²⁻ ion with a satisfactory agreement.