Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
Pressure-Induced Quantum Ferroelectricity in Tris-Sarcosine Calcium Bromide ((CH3NHCH2COOH)3CaBr2)
Tomoyuki HikitaTaketoki Maruyama
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1992 Volume 61 Issue 8 Pages 2840-2847

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Abstract
Dielectric properties of tris-sarcosine bromide ((CH3NHCH2COOH)3CaBr2) which is isomorphous to the ferroelectric crystal tris-sarcosine calcium chloride ((CH3NHCH2COOH)3CaCl2, TSCC) have been investigated under high pressure down to 4.2 K. The hydrostatic pressure of excellent quality has been generated using helium gas as a pressure transmitting medium. The ferroelectric activity has been confirmed by the dielectric hysteresis loops. The pressure-temperature phase diagram of the ferroelectric phase transition is determined from the peak of the dielectric constant of the b-plate in various isobaric measurements. The transition temperature is well represented by an equation TC∝(ppC)1⁄2 which is a well known relationship for quantum ferroelectrics.
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