Abstract
Behavior of sulfur in high temperature oxidation of Fe-20Cr-4Al alloys with 491, 1300 and 6300ppm of sulfur was studied at 1473K for 18.0ks in 1 bar of oxygen. Mass changes of these alloys after the oxidation were almost the same of 0.60×10-2kg/m2. The oxide scales with good adhesion on each alloys were analysed as α-Al2O3 by XRD analyses. Observation of indentation by hardness measurement suggested that a highly ductile scales were formed on these alloys.