Netsu Sokutei
Online ISSN : 1884-1899
Print ISSN : 0386-2615
ISSN-L : 0386-2615
Special Issue - Soft Matter Physical Chemistry -
Measurement of Hansen Solubility Parameter of Ionic Liquids
Daiki TsutsumiYusuke AgataHideki Yamamoto
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2022 Volume 49 Issue 1 Pages 26-29

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Abstract
The Hansen solubility parameters (HSPs) of some ionic liquids with different combinations of cations and anions were measured and calculated. The Hansen solubility sphere method was used to calculate the HSPs of ionic liquids from experimental data on the solubility evaluation of the ionic liquids in some organic solvents. It was found that the double-sphere method rather than the general single-sphere method was suitable for this evaluation. For double-sphere analysis, the high polarity side sphere represents an ionic domain and the nonpolar side sphere represents a neutral domain. The value as the center of each sphere was assumed to be the HSP for each domain. The calculation results confirmed that the positions of the double-sphere in Hansen’s 3D-diagram for the ionic liquid depended on the types of cation and anion.
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© 2022 The Japan Society of Calorimetry and Thermal Analysis
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