Netsu Sokutei
Online ISSN : 1884-1899
Print ISSN : 0386-2615
ISSN-L : 0386-2615
Review
Thermal Property Enhancement of Biopolyesters by Controlling Molecular Structure and Processing Conditions
Daisuke Ishii
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2024 Volume 51 Issue 4 Pages 153-159

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Abstract
In order to enhance thermal properties of biomass plastics, i.e., plastics made from plant biomasses, modification of backbone structure and processing conditions have been attempted. As the modification of backbone structure, utilization of cinnamic acid derivatives in the polyester was found effective to enhance the glass transition and degradation temperatures. In particular, utilization of ferulic acid led to express liquid crystalline nature. As the modification of processing conditions, utilization of polysaccharide derivatives as the nucleating agent of poly(lactide) stereocomplex was attempted. As the result, enhanced stereocomplex formation without homocrystal formation after the isothermal crystallization below the melting point of homocrystal was attained.
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© 2024 The Japan Society of Calorimetry and Thermal Analysis
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