Netsu Sokutei
Online ISSN : 1884-1899
Print ISSN : 0386-2615
ISSN-L : 0386-2615
Evolution of Novel Functions in Perovskite-related Oxides by Controlling Structures and the Chemical Bonds
Mitsuru Itoh
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1999 Volume 26 Issue 3 Pages 64-75

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Abstract
Relationship between physical properties and structure or chemical bond in perovskite-related oxides has been briefly explained. Magnetic interactions are mainly depending on the local structures of B-O-B sequence and the electronic state of transition metal ions can be controlled by tuning the competing A-O and B-O bonds. Origin of the high temperature quantum paraelectricity in perovskite titanate was explained by the repulsion and Coulomb forces between Ti-O bonds. An example of the control of quantum paraelectricity to quantum ferroelectricity in SrTiO3 was introduced.
Finally, ionic conduction in perovskite-related oxides was briefly reviewed.
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© Japan Society of Calorimetry and Thermal Analysis
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