The Review of High Pressure Science and Technology
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
Reviews -Challenges to Possibility of High-Pressure Science and Technology-
Effect of High Pressure on Phase Equilibria of Mixtures Containing Liquid Crystals
Yoshiyuki TANAKAMing YANGTomohiro SOTANIShigenobu MATSUOMasato MORITOKI
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JOURNAL FREE ACCESS

2003 Volume 13 Issue 2 Pages 119-126

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Abstract
In this article, recent advances in the fundamental high pressure research for the phase equilibria of mixtures containing liquid crystals were reviewed. The effect of pressure on the crystal-nematic and nematic-isotropic phase transition temperatures, TCN and TNI, was investigated for MBBA (n-(4-methoxybenzylidene)-4-n-butylaniline), EBBA(n-(4-ethoxybenzylidene)-4-n-butylaniline), and binary mixtures containing these components such as (MBBA+EBBA), and (MBBA, EBBA+ benzene, n-hexadecane) at temperatures from 263 to 363 K and pressures up to 200 MPa. The measurements of TCN and TNI were performed using a compact high-pressure optical vessel designed for direct visual observation with the aid of a video microscope, and a three-terminal cylindrical capacitor for dielectric study. The effects of pressure and admixing of a nematic and non-mesogenic second component on the phase transitions are discussed.
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© 2003 The Japan Society of High Pressure Science and Technology
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