The Review of High Pressure Science and Technology
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
In Situ X. Ray Observation of the Phase Transitions from α to γ and from γ to Perovskite+Periclase in Mg2SiO4
T. KatoT. KuboH. MorishimaE. OhtaniA. SuzukiD. YamazakiK. MibeT. KikegawaO. Shimomura
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1998 Volume 7 Pages 119-121

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Abstract
In situ X-ray observation has been made on Mg5SiO4 forsterite in the pressure ranges over 25-30 GPa and 1250°C using double stage multianvil system with sintered diamond anvil window and intense X-rays from synchrotm radiation. Forsterite (α-phase) transfomed into spinel (γ-phase) at 28 GPa and 800°C in the fist heating cycles of the two runs. Spinel transformed into the assemblage of perovskite and periclase in the second heating cycless at 26. 4 GPa and 1200°C and at 28. 5 GPa and 950°C. The results show that α-γ transition can proceed outside the stability field of spinel, and that the blocking temperature, above which the stable assmblage of perovskite and periclase can be formed, has a pressure dependence.
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