B213 A Study of the Density Fluctuation of Diatomic Fluids around the Critical Point by Molecular Dynamics Simulation

Abstract

In this study, we evaluated the density fluctuation of diatomic fluids around the critical point. We performed Molecular Dynamics (MD) simulation against 2-Center-Lenard-Jones (2CLJ) fluids that have molecular elongation as a parameter. We compared the density fluctuation of each fluid to evaluate the principle of corresponding state of density fluctuation. We evaluated the density fluctuation by dispersion of number of molecules, static structure factor, and intermediate scattering function. As the results, in 2CLJ fluids that have shorter molecular elongation comparatively, the principle of corresponding state of static fluctuation structure was satisfied.