Journal of the Society of Materials Science, Japan
Online ISSN : 1880-7488
Print ISSN : 0514-5163
ISSN-L : 0514-5163
Photocatalystic Effect of Rust on Acid Rain Corrosion of Carbon Steel
Makoto KUMADAKazuya SHINODAShigetoshi KOBUCHIKiyoko NIWATakahiro YAMADA
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1999 Volume 48 Issue 11 Pages 1239-1243

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Abstract
The effect of ultra-violet (UV) light irradiation on corrosion behavior of carbon steel in acid rain was investigated by immersion tests and electrochemical measurement. From the result it was found that (1) corrosion loss of the steel in artificial acid rain increased with decrease of solution pH, (2) corrosion loss and anodic current density of the steel under UV irradiation was larger than those without UV irradiation, and (3) the effect of UV irradiation on corrosion of the steel increased with immersion time. It is considered that the rust on the carbon steel acts as a photocatalyst and to enhance the corrosion in acid rain. From a semiconductive property of the rust, we proposed an enhancement mechanism of the corrosion by UV light irradiation.
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