Journal of the Society of Materials Science, Japan
Online ISSN : 1880-7488
Print ISSN : 0514-5163
ISSN-L : 0514-5163
Syntheses and Luminescent Properties of (La1-xLnx)2O2CN2(Ln=Pr, Sm, Eu, Tb)
Masao TAKAHASHIYasuhiro HASHIMOTOShinichi KIKKAWAHikaru KOBAYASHI
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2000 Volume 49 Issue 11 Pages 1230-1234

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Abstract
Several rare earth doped lanthanum dioxymonocyanamide phosphors have been prepared by calcining mixture of La2O3 and rare-earth oxide powders under flowing ammonia gas in the existence of carbon. Incorporated rare earth ions worked as a luminescence center. Colors of the luminescence of these phosphors irradiated by the monochromatized x-ray of 9keV were pale blue, reddish purple, red and green for Pr, Sm, Eu and Tb, respectively. For optical luminescence spectra measured for (La1-xEux)2O2CN2 at room temperature, the relation between the fluorescence intensity and Eu content, x was discussed with the solid solution limit of Eu to La2O2CN2, estimated by the XRD and XANES analyses.
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