Hyomen Kagaku
Online ISSN : 1881-4743
Print ISSN : 0388-5321
ISSN-L : 0388-5321
Special Issue on Frontiers of Surface Vibrational Spectroscopy
A Study of the Vibrational States of Adsorbed Hydrogen by EELS
Hiroshi OKUYAMA
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2003 Volume 24 Issue 5 Pages 295-300

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Abstract
Vibrational states of H adsorbed on Ni(111) have been investigated by means of electron energy loss spectroscopy (EELS). In addition to the symmetric (νs) and asymmetric (νas) fundamental modes, the corresponding overtone structures are clearly detected. The overtone of νas, the predominantly parallel-polarized mode, exhibits a doublet structure at 0.5 ML, which is interpreted to result from the delocalization of the excited vibrational states. On the other hand, at high coverage (1.0 ML), the repulsive interactions between the adsorbed hydrogen promote the localization of the vibrational states, and the vibrational excitations are found to be collective (adsorbate phonons). The phonon dispersions are measured along the ΓM direction of the surface Brillouin zone, where we find the evidence of the two-phonon bound states. Applying a one-dimensional model of coupled anharmonic oscillators, we derive the anharmonicity and discuss the localized property of the vibrations.
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この記事はクリエイティブ・コモンズ [表示 - 非営利 4.0 国際]ライセンスの下に提供されています。
https://creativecommons.org/licenses/by-nc/4.0/deed.ja
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