A Kinetic of Chemical Reaction in Heterogeneous System.

Abstract

We have developed a kinetic theory of heterogeneous reaction for the purpose of analysing combustion velocity of solids.
By this theory, generalized reaction rate is given as follow :
dz/dt = (S_o/Q) Φ(z) (KΔμ)/((1/k)+(1/γD ∫^II _I dx))
   here, S_o :   initial surface area,
    Q :   initial mass,
    Φ(z)  :   shape function,
    K,γ :   a constant,
    D :   diffusion constant,
     k :   velocity constant in reaction,
     Δμ :   chemical potential,
  ∫^II _I dx :   thickness of diffusion layer,
So we can obtain the required equation by substituting Φ(Z) and proper conditions for this formula.