Transactions of the Japan Society of Mechanical Engineers Series B
Online ISSN : 1884-8346
Print ISSN : 0387-5016
Effects of Internal Leak Current on PEFC Output Voltage
Internal Leak Current at Open Circuit and Close Circuit in Smaller Current Density Region
Toshiaki KONOMIAtsushi KAWAKAMIHideaki TACHIBANA
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2005 Volume 71 Issue 712 Pages 3025-3030

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Abstract

Over voltages and internal leak current density in PEFC were analyzed by FFT impedance method. Results showed that the conventional coefficient of Butler·Volmer's equation was twice as theoretical one. The coefficient measured by FFT impedance method was corresponding to the theoretical one. Measured internal leak current density in PEFC is 7.5 mA/cm2, and it reduces output voltage from 3 to 13 mV. Sum of the over voltages by the leak current and the known is 20-30%lower than Nernstian theoretical potential. Analysis and improvement of the unknown over voltages such as mixed potential and so on, will make big performance increase in PEFC.

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