Abstracts of Symposium on Physical Organic Chemistry
18th. Symposium on Fundamental Organic Chemistry
Session ID : 3PC63
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Co-host: Symposium on Fundamental Organic Chemistry

Structures and Properties of Radical Salts Based on a Pyridinium Derivative with Stable Radical and Transition-Metal Complexes
*Bilkish Rahman, Hiroki Akutsu, Jun-ichi Yamada, Shin'ichi Nakatsuji
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Keywords: Stable Radical, TEMPO Radical, Transition-Metal Complex, Magnetic Property, Conducting Property
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Abstract
Starting from TEMPO-substituted pyridinium fluoroborate, some of the corresponding Ni(dmit)2, Pd(dmit)2, and Ni(mnt)2 salts were prepared. Among them, the corresponding salt with (1:6) radical cation-to-anion ratio was obtained by oxidation of the Ni(dmit)2 or Pd(dmit)2 salt, showing semi-conductive property with relatively high room temperature conductivity. The structures and magnetic properties of the radical salts prepared will be reported.
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© 2006 by Symposium on Organic Reactions
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