Abstracts of Symposium on Physical Organic Chemistry
18th. Symposium on Fundamental Organic Chemistry
Session ID : 3PC67
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Co-host: Symposium on Fundamental Organic Chemistry

Generation and Characterization of 9-Acridylcarbene
*Katsuyuki Hirai, Chinami Kawai, tetsuji Itoh, Toshikazu Kitagawa, Hideo Tomioka
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Keywords: Triplet Carbene, Diazo Compound, Photolysis, Copper Complex, Magnetic Properties
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Abstract
In order to prepare organic magnetic materials, we have studied persistent high-spin polycarbenes. As a part of this research, 9-acrydyl(phenyl)diazomethane was synthesized and triplet carbene generated by photolysis of this diazo compound was characterized by spectroscopic means. Magnetic properties of photoproducts from a complex of 9-acrydyl(phenyl)diazomethane N-oxide and copper ion is also described.
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© 2006 by Symposium on Organic Reactions
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