Abstracts of Symposium on Physical Organic Chemistry
20th Symposium on Physical Organic Chemistry
Session ID : 3P79
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Host: Symposium on Physical Organic Chemistry

Poster Presentation
Confomational Effect of Leaving group OTS on Charge Delocalization in Solvolysis
*Ryoji Fujiyama, Yuka Masaoka, Satoshi Umedu, Daishi Katsu, Daisuke Kaneno, Mizue Fujio
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Keywords: Conformation, Charge delocalization, Carbocation, Solvent Effect, Solvolysis, ab initio MO
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Abstract
The conformational effect of leaving groups alcohols and tosylates on the charge delocalization in the solvolyses of β–arylalkyl systems was examined by ab initio molecular orbital calculation, compared with the charge delocalization parameter derived from the Tsuno-Fujio equation.
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© 2009 by the Organizing Comittee of 20th Symposium on Physical Organic Chemistry
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