Abstracts of Symposium on Physical Organic Chemistry
22nd Symposium on Physical Organic Chemistry
Session ID : C21
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Location C
Synthesis and properties of various oligo-TTF with alkylenedithio linker
*Ken-ichi Nakamura, Tomomi Hashimoto, Ryota Shiba, Yumi Baba, Takashi Shirahata, Masashi Hasegawa, Yasuhiro Mazaki, Yohji Misaki
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Keywords: Tetrathiafulvalene, Oligomer, face-to-face interaction, Mixed valence
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Abstract
It is well known that Tetrathiafulvalene (TTF) is most popular donor component of molecular conductor. The appearance of metallic conductivity in cation radical salt of TTF requires intrastacked mixed valence interaction. Investigation of oligo-TTF units contributes to understand face-to-face interaction between the TTF units. Thus, we report the synthesis and properties of TTF oligomer with flexible alkylenedithio linker.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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