Abstracts of Symposium on Physical Organic Chemistry
22nd Symposium on Physical Organic Chemistry
Session ID : 1P035
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Poster Session (The 1st day)
Synthesis and fluorescence properties of thiophene-fused 3-methylene-2,3-dihydrothiophene derivatives
*Shota Kobayashi, Norio Nakata, Akihiko Ishii
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Keywords: sulfur, thiophene, fluorescence, intramolecular cycloaddition, dibenzobarrelene
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Abstract
Thiophene-fused 3-methylene-2,3-dihydrothiophene derivatives 2 were synthesized by intramolecular [4+2] cycloaddition of 2-alkynyl-3-(9-anthrylthio)thiophene derivatives 1. These derivatives showed blue fluorescence in a CH2Cl2 solution and phenyl-substitution derivative indicated relatively strong fluorescence in a solid stat
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© 2011 by The Society of Physical Organic Chemistry, Japan
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