Abstracts of Symposium on Physical Organic Chemistry
22nd Symposium on Physical Organic Chemistry
Session ID : A15
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Location A
Synthesis and Characterization of a Novel Cyclophane Consisting of 6,13-Dihydropentacene
*Akikazu MATSUDA, Tomoyuki TAJIMA, Yutaka TAKAGUCHI
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Keywords: Cyclophane, Dihydropentacene, Fluorescence, Naphthalene
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Abstract
A novel cyclophane consisting of 6,13-dihydoropentacene was synthesized via ring-closing metathesis in 16% yield. Interestingly, the compound exhibited about 75 nm red shift in emission spectrum compared to non-cyclized precursor.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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