Abstracts of Symposium on Physical Organic Chemistry
22nd Symposium on Physical Organic Chemistry
Session ID : 1P080
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Poster Session (The 1st day)
Preparation and Properties of a Ladder-Type Assembly of Porphyrin Trimers with Excitation Energy Gradient
*Akiko TsutsumiAtsuhiro UetomoMasatoshi KozakiShuichi SuzukiKeiji Okada
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CONFERENCE PROCEEDINGS FREE ACCESS

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Abstract
We synthesized a linear porphyrin trimer (TPP-DEP-TPP) that has a meso-diethynyl Zn-porphyrin unit (DEP) and two tetraphenyl Zn-porphyrin terminals (TPP). The trimer formed stable 1:3 and 2:3 complexes in chloroform with 4-phenylpyridine and 4,4'-biphyridine, respectively. The complexation of the trimer was investigated by means of UV-vis titration. The detailed synthetic procedure and complexation of the trimer with several ligands will be presented.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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