Abstracts of Symposium on Physical Organic Chemistry
22nd Symposium on Physical Organic Chemistry
Session ID : A04
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Location A
Preparation and Characterization of Donor-type Self-assembled Monolayers Containing Silyl Terminal
*Hiroki MuraokaTakao NishikawaSatoshi Ogawa
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CONFERENCE PROCEEDINGS FREE ACCESS

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Abstract
We prepared and characterized donor-type self-assembled monolayers (SAMs) to apply n-type organic field effect transistors (OFET). We have designed and synthesized a series of tetrathiafulvalene derivatives fused to benzene, 1,4-dithiane and 1,4-dioxane having triethoxysilyl groups as an anchor unit to prepare the self-assembled monolayers (SAMs) possessing charge transfer ability. The layer properties of SAMs on the silicon dioxide covered with these compounds were fully characterized by X-ray photoelelectron spectroscopy (XPS) and water contact angle (WCA). The OFET characteristics modified by the SAM and cupper hexadecafluorophthalocyanine as a semiconducting layer will be discussed in the presentation.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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