電子吸引基をもつTTFオリゴマーの合成と性質

中村 健一; 高島 毅; 長谷川 真士; 宮本 久一; 御崎 洋二

doi:10.11494/kisoyuki.37.0.195.0

37th Symposium on Structural Organic Chemistry

DOI https://doi.org/10.11494/kisoyuki.37.0.195.0

Conference information

Host: The executive committee of the 37th symposium on structrual organic chemistry

Co-host: The Chemical Society of Japan, The Hokkaido Branch of the Chemical Society of Japan, Hokkaido University, Global COE (chemistry),, "Catalysis as a Basis for Innovation in Material Sciences ", The Society of Synthetic Organic Chemistry, Japan

poster presentation

Syntheses and properties of TTF oligomers with electro-withdrawing groups

*Kenichi Nakamura, Tsuyoshi Takashima, Masashi Hasegawa, Hisakazu Miyamoto, Yohji Misaki

Author information

Keywords: tetrathiafulvalene, electro-withdrawing groups, molecular wire, stacking structure, oligomer

CONFERENCE PROCEEDINGS FREE ACCESS

Pages 195

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Abstract

TTF and its derivative are known to form conductive pass along the stacking direction in their conductive complexes. On the other hand, TTF molecules with electron withdrawing groups have received considerable attention as single-component molecular conductors because they have narrow HOMO-LUMO gap conductive monomolecular.In this study, we report synthesis and properties of TTF molecules with electro-withdrawing groups such as cyano and ester groups as a model compound of a molecular wire with TTF stacks.

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