Abstracts of Symposium on Physical Organic Chemistry
53rd Symposium on Organic Reactions
Session ID : O-19
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Co-host: The Chemical Society of Japan, The Chemical Society of Japan, Kyushu Branch, The Society of Synthetic Organic Chemistry, Japan (Cooperation)

The Eeactions of Acetylenic Ethers
*Shinjiro Kobayashi, Thomas Tidwell
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Keywords: thermolysis, alkyl acetylenic ether, 1,5-hydrogen shift, 1,4-hydrogen shift
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Abstract
Thermolysis of trimethylsilylethynyl alkyl ether is known a method to make anisolabletrmethylsilylketene via 1,5-shift of the hydrogen atom on the β-carbon. The effect of introductionof a phenyl group on the alkyl group will be discussed.
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© 2003 by Symposium on Fundamental Organic Chemistry
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