フッ素化フラーレンの電子移動還元反応

大久保 敬; Taylor Roger; Boltalina Olga V.; 福住 俊一

doi:10.11494/kisoyuki.53.0.59.0

53rd Symposium on Organic Reactions

Session ID : P-35

DOI https://doi.org/10.11494/kisoyuki.53.0.59.0

Conference information

Co-host: The Chemical Society of Japan, The Chemical Society of Japan, Kyushu Branch, The Society of Synthetic Organic Chemistry, Japan (Cooperation)

Electron Transfer Reduction of Fluorinated Fullerenes

*Kei Ohkubo, Roger Taylor, Olga V. Boltalina, Shunichi Fukuzumi

Author information

Keywords: fullerene, defluorination, reduction, electron transfer, ESR

CONFERENCE PROCEEDINGS FREE ACCESS

Details

Abstract

Electron transfer reduction of C₆₀F₁₈ to the defluorinated anion, C₆₀F₁₇^- occurs efficiently by a relatively weak one-electron reductant, p-chloranil radical anion; the one-electron reduction potential of C₆₀F₁₈ is evaluated as 0.04 V (vs. SCE) by comparison of the rate constant for electron transfer from 10,10'-dimethyl-9,9',10,10'-tetrahydro-9,9'-biacridine to C₆₀F18 with those of other one-electron reductants. Electron transfer reduction properties of C₆₀F₃₆ are also reported.

Corresponding author

Register with J-STAGE for free!