Abstracts of Symposium on Physical Organic Chemistry
53rd Symposium on Organic Reactions
Session ID : P-55
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Co-host: The Chemical Society of Japan, The Chemical Society of Japan, Kyushu Branch, The Society of Synthetic Organic Chemistry, Japan (Cooperation)

Alkoxy Group Effect of on the Reactivity of 2,2-Dialkoxy-1,3-diradicals
*Masanori Hattori, Manabu Abe, Masatomo Nojima
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Keywords: alkoxy-group effect, 1,3-diradical, substituent effect
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Abstract
Alkoxy group effect at C2 position in 1,3-diradicals has attracted considerable attention from the substituent effect on the singlet-triplet energy gap and their chemical reactivity. In the present study, we have investigated the effect of the spiro-configured ethylene-acetal functionality. The ethylene-acetal functionality produces not only the lager singlet-triplet energy gap in 1,3-diradicals, but also the reactivity of the cyclopentane-1,3-diyls, when compared with the 2,2-dimethoxy substituted one.
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© 2003 by Symposium on Fundamental Organic Chemistry
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