Abstracts of Symposium on Physical Organic Chemistry
53rd Symposium on Organic Reactions
Session ID : P-61
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Co-host: The Chemical Society of Japan, The Chemical Society of Japan, Kyushu Branch, The Society of Synthetic Organic Chemistry, Japan (Cooperation)

The Synthesis in Room Temperature Ionic Liquids of Porphyrin Derivatives
*Satoshi Kitaoka, Kaoru Nobuoka, Yuichi Ishikawa
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Keywords: ionic liquid, tetraphenyl porphyrin, aluminium chloromate, Lewis acid
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Abstract
At present, Ionic liquid attracts the attention as a green solvent. Actually, various synthesis as Diels-Alder reactions, Heck reactions are reported. In this study, this ionic liquid was used as reaction solvent of the TPP synthesis. In the experiment, the ionic liquid which made imidazolium ion to be the cationic skeleton was used. As the result, it succeeded in synthesizing TPP in the ionic liquid as an anion with aluminum chloride (III) at 3.6% yield.
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© 2003 by Symposium on Fundamental Organic Chemistry
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