Kobunshi Kagaku
Online ISSN : 1884-8079
Print ISSN : 0023-2556
ISSN-L : 0023-2556
Studies on the Solutions of Acrylonitrile Polymers
II. Solubility of Polyacrylonitrile and its related Polymers
Kazuo MiyamichiMasamichi Katayama
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1960 Volume 17 Issue 187 Pages 675-678

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Abstract
The solvent power of dimethylsulfoxide was compared with that of dimethylformamide for the following polymers: polyacrylonitrile, acrylonitrile-methylacrylate copolymers, polyvinylalcohol, polyvinylchloride, polyvinylacetate, polymethylacrylate and polystyrene. Solubility of the heat-treated films, intrinsic viscosity and the “dilution ratio”of the solutions were used as a measure of the solvent power. It was found that dimethylsulfoxide is better solvent than dimethylformamide for the polymers having great cohesive energy density, such as polyvinylalcohol and polyacrylonitrile.
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© The Society of Polymer Science, Japan
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